Study on synthesis and crystal structure of tri(o-chlorobenzyl) tin 3-indolylacetate

被引：0

作者：

Wang, JQ ^{[1
]}

Zhang, FX ^{[1
]}

Kuang, DZ ^{[1
]}

Feng, YL ^{[1
]}

机构：

[1] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 24卷 / 07期

关键词：

tri(o-chlorobenzyl)tin; 3-indolylacetate; synthesis; crystal structure;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The novel complex tri ( o -chlorobenzyl) tin 3-indolylacetate has been synthesized. The crystal structure of the complex was determined by X-ray diffraction study. The crystal belongs to triclinic system with space group P-1 with a=0.8376(3) nm, b = 1.1118(3) nm, c = 1.6557(5) nm, alpha = 102.747(5)degrees, beta = 101.238(5)degrees, gamma = 107.683(5)degrees, V= 1.4382(8) nm(3), Z=2, D-c= 1.549 g/cm(3), mu(Mo Kalpha) = 11.96 cm(-1), F(000) =674, R-1 = 0.0369, Rw=0.0785; The bond lengths of Sn-C are 0.2143(4), 0.2153(4) and 0.2161(4) nm. The Sn-O is 0.2072(3) nm. The tin atom has a distorted tetrahedral geometry.

引用

页码：815 / 818

页数：4