Solid-state complexes of quinoxaline- and phenazine-N,N'-dioxide donors with tetracyanoethylene. Crystal engineering via donor-acceptor interactions

被引：17

作者：

Greer, ML ^{[1
]}

Duncan, JR ^{[1
]}

Duff, JL ^{[1
]}

Blackstock, SC ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35487

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 44期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(97)10089-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,3-Dimethylquinoxaline-N,N'-dioxide (DMQDO) and phenazine-N,N'-dioxide (PDO) bind to tetracyanoethylene (TCNE) in solution, with complexation constants of 4.8(7) and 1.2(7) M-1 respectively in CH2Cl2. Crystallization of the mixtures affords two-component solids which contain weakly bound one-dimensional donor-acceptor arrays. The DA interactions create DA ladder domains in the (DMQDO)(2)TCNE solid and single-stranded DA chains in the (PDO)TCNE crystal. (C) 1997 Elsevier Science Ltd.

引用

页码：7665 / 7668

页数：4

共 9 条

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