Chiral Zn-salen complexes: a new class of fluorescent receptors for enantiodiscrimination of chiral amines

被引：28
|
作者：
Puglisi, Roberta [1 ]
Ballistreri, Francesco P. [1 ]
Gangemi, Chiara M. A. [1 ]
Toscano, Rosa Maria [1 ]
Tomaselli, Gaetano A. [1 ]
Pappalardo, Andrea [1 ,2 ]
Sfrazzetto, Giuseppe Trusso [1 ]
机构：
[1] Univ Catania, Dept Chem Sci, Viale Andrea Doria 6, I-95125 Catania, Italy
[2] INSTM Udr Catania, Viale Andrea Doria 6, I-95125 Catania, Italy
来源：
NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 03期
关键词：
SCHIFF-BASE COMPLEXES; ENANTIOMERIC RECOGNITION; EPOXIDATION; CAVITANDS; CATALYSTS; DERIVATIVES; INDUCTION; OLEFINS; EXCESS; NMR;
D O I：
10.1039/c6nj03592b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first example of fluorescent chiral Zn-salen hosts, able to efficiently recognise chiral amines via non-covalent interactions, is reported here. The host-guest interactions have been characterised by 2D-NMR spectroscopy in order to elucidate the origin of enantioselectivity.
引用
收藏
页码：911 / 915
页数：5
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