PtCl(PHCy2){(PCy2O)2H}:: a hydrogen bonded phosphinito complex obtained by direct reaction of molecular oxygen with a terminal phosphido complex

被引：15
|
作者：
Mastrorilli, P
Latronico, M
Nobile, CF
Suranna, GP
Fanizzi, FP
Englert, U
Ciccarella, G
机构：
[1] Politecn Bari, Dipartimento Ingn Acque & Chim, I-70125 Bari, Italy
[2] Univ Basilicata, DIFA, I-85100 Potenza, Italy
[3] Univ Lecce, Dipartimento Sci & Tecnol Biol & Ambientali, I-73100 Lecce, Italy
[4] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52074 Aachen, Germany
[5] Univ Lecce, Dipartimento Ingn Innovaz, I-73100 Lecce, Italy
来源：
DALTON TRANSACTIONS | 2004年 / 08期
关键词：
D O I：
10.1039/b402180k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Exposure of solid trans-[Pt(PHCy2)(2)(PCy2)Cl] (1) to dry oxygen unexpectedly leads to [PtCl(PHCy2){(PCy2O)(2)H}] (2) as the major product, the formation of which has been followed by NOESY H-1 NMR techniques.
引用
收藏
页码：1117 / 1119
页数：3
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