A novel azobenzene covalent organic framework

被引：67
|
作者：
Zhang, Jian [1 ]
Wang, Laibing [1 ]
Li, Na [1 ]
Liu, Jiangfei [1 ]
Zhang, Wei [1 ]
Zhang, Zhengbiao [1 ]
Zhou, Nianchen [1 ]
Zhu, Xiulin [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Suzhou 215123, Peoples R China
来源：
CRYSTENGCOMM | 2014年 / 16卷 / 29期
关键词：
RETICULAR SYNTHESIS; FACILE SYNTHESIS; CARBON-DIOXIDE; CRYSTALLINE; POLYMERS; FUNCTIONALIZATION; CONSTRUCTION; ADSORPTION; ELECTRON; HYDROGEN;
D O I：
10.1039/c4ce00369a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel azobenzene (Azo) monomer was synthesized and employed to produce Azo-containing covalent organic frameworks (Azo-COF) through the borate ester formation reaction. The trans-to-cis photoisomerization of Azo units in Azo-COF occurred under irradiation with 365 nm UV light. The photoisomerization of Azo units could decrease the crystallinity of Azo-COF but could not change the pore size of Azo-COF.
引用
收藏
页码：6547 / 6551
页数：5
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