Effective and sustainable LCO upgrading using distillation and co-hydroprocessing with waste cooking oil

被引:1
|
作者
Dagonikou, Vasiliki [1 ,2 ]
Bezergianni, Stella [1 ]
Karonis, Dimitrios [2 ]
机构
[1] Ctr Res & Technol Hellas CERTH, Chem Proc & Energy Resources Inst CPERI, 6th Km Harilaou Thermis, GR-57001 Thessaloniki, Greece
[2] Natl Tech Univ Athens, Zografou Campus 9,Iroon Polytech Str, Athens 15780, Greece
关键词
LCO; Distillation; WCO; Co-hydroprocessing; LIGHT CYCLE OIL; CATALYTIC HYDROTREATMENT; GAS-OIL; DIESEL; SATURATION; UNIT;
D O I
10.1016/j.fuproc.2020.106676
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The technology of distillation and the technology of co-hydroprocessing with liquid biomass are combined for a more effective and sustainable LCO upgrading. The first technology is to separate the LCO hydrocarbons via distillation to obtain the fraction with boiling point up to 350 degrees C, rendering a light LCO fraction (LCO_cut). The second technology involves the integration of the LCO_cut with Waste Cooking Oil (WCO) towards a joined hydrotreatment step. The choice of the two aforementioned technologies is based on the claim that the distillation will exempt LCO from refractory properties and the co-hydroprocessing with WCO will led to a paraffinic product that could approach diesel fuel quality. The results show that concerning sulfur content, an improvement presented in the case of LCO_cut/ WCO product in comparison with the corresponding ones of LCO/ WCO. Moreover, the LCO_cut/ WCO product of the intermediate temperature presented the optimal aromatic content, density and cetane number in comparison with the corresponding ones of LCO/ WCO. In summary, the two degraded feedstocks; LCO and WCO, are converted to improved products, indicating the potential of integrating these feedstocks within a refinery.
引用
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页数:5
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