SYNTHESIS AND COORDINATION PROPERTIES OF TRIPODAL LIGAND ON THE TRIPHENYLPHOSPHINE OXIDE PLATFORM WITH CARBAMOYL SIDE ARMS

被引:10
|
作者
Kudryavtsev, Igor Yu. [1 ]
Baulina, Tat'yana V. [1 ]
Pasechnik, Margarita P. [1 ]
Matveev, Sergei V. [1 ]
Matveeva, Anna G. [1 ]
机构
[1] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
关键词
Tripodal phosphine oxide; complexes; f-elements; IR; NMR; LANTHANIDE NITRATE COMPLEXES; MOLECULAR-STRUCTURE; SOLVENT-EXTRACTION; CRYSTAL-STRUCTURE; URANYL-NITRATE; SOLID-STATE; EFFICIENT; RECEPTORS; BEHAVIOR; DENSITY;
D O I
10.1080/10426507.2014.904865
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new tripodal O-donor ligand, tris(2-N, N-dibutylcarbamoylmethoxyphenyl) phosphine oxide (L), was synthesized. This potentially tetradentate ligand L exhibits variable denticity upon complexation with UO2(NO3)(2), Nd(NO3)(3), and Lu(NO3)(3). The complexes were studied by elemental analysis, IR, and H-1, C-13, and P-31 NMR spectroscopy. [Supplementary materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental files: Additional text, tables, and figures.]
引用
收藏
页码:946 / 962
页数:17
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