Construction of achiral/chiral coordination polymers with helical structures based on an imidazole-based dicarboxylate ligand containing the trifluoromethyl group

被引：11

作者：

Li, Tian-Tian ^{[1
]}

Huang, Xuan ^{[2
,3
]}

Guo, Jun-Gu ^{[2
,3
]}

Cai, Song-Liang ^{[2
,3
]}

Zheng, Sheng-Run ^{[2
,3
]}

机构：

[1] GuiYang Coll Tradit Chinese Med, Guiyang 550002, Peoples R China

[2] S China Normal Univ, Inst Special Mat, Guangzhou 510006, Guangdong, Peoples R China

[3] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 48卷

基金：

中国国家自然科学基金;

关键词：

Coordination polymer; Imidazole-based dicarboxylate acid ligand; Helical structure; Luminescence property; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; DIVERSITY; LUMINESCENCE; ADSORPTION; NETWORKS; CLUSTERS; SERIES;

D O I：

10.1016/j.inoche.2014.07.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new coordination polymers, {[Pb(mu(2)-H2TFMIDC)(2)-(mu(2)-H2O)]center dot.H2O}(n) (H3TFMIDC = 2-(trifluoromethyl)-4,5-imidazole dicarboxylic acid, 1) and [Ba(mu(2)-H2TFMIDC)(mu(4)-H2TFMIDC)(H2O)](n) (2), were constructed under hydrothermal/solvothermal conditions. Compound 1 is an achiral 3D framework based on irregular helical chains and displays a 6-connected pcu network topology. Compound 2 exhibits a 3D chiral framework based on homochiral 1D helical chains with a (4,8)-connected network topology. The luminescence properties of compounds 1-2 were also investigated. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：61 / 64

页数：4

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