Crystallization behaviors and mechanical properties of carbon fiber-reinforced polypropylene composites

被引:36
|
作者
Tian, Huafeng [1 ,2 ]
Zhang, Shuai [1 ]
Ge, Xiang [1 ]
Xiang, Aimin [1 ]
机构
[1] Beijing Technol & Business Univ, Sch Mat & Mech Engn, Beijing 100048, Peoples R China
[2] Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon fiber; Polypropylene; Mechanical properties; Crystallization behaviors; ISOTACTIC POLYPROPYLENE; ELECTRICAL-PROPERTIES; NANOCOMPOSITES; POLYETHYLENE; MORPHOLOGY; DIOXIDE; SILICA; BLEND;
D O I
10.1007/s10973-016-5996-3
中图分类号
O414.1 [热力学];
学科分类号
摘要
In this work, carbon fiber (CF)-reinforced polypropylene (PP) composites were prepared by melt processing with maleic anhydride-grafted polypropylene as compatibilizer. The mechanical properties and crystallization behaviors of the resulting composites were investigated detailedly. The interfacial compatibility of CRP composites was fine and CF dispersed in PP matrix homogeneously. CF played a nucleation agent for the crystallization of PP. The crystallization temperature increased with increasing CF content. Carbon fibers could act as the heterogeneous nucleation agent for PP, which would decrease the activation energy of crystallization, shorten the crystallization time and raise the crystallization rate dramatically. The original spherulite morphology of neat PP was also destroyed by CF. CF exhibited obvious reinforcing effects on PP matrix and improved the mechanical properties of PP materials. The tensile strength and flexural strength were increased over 100% with 20 mass% CF.
引用
收藏
页码:1495 / 1504
页数:10
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