Dynamic motion of building blocks in porous coordination polymers

被引：211
|
作者：
Horike, Satoshi
Matsuda, Ryotaro
Tanaka, Daisuke
Matsubara, Seijiro
Mizuno, Motohiro
Endo, Kazunaka
Kitagawa, Susumu [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Nishikyo Ku, Kyoto 6158510, Japan
[3] Kanazawa Univ, Grad Sch Nat Sci & Technol, Dept Chem, Kanazawa, Ishikawa 9201192, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 43期
关键词：
cadmium; coordination polymers; metal-organic frameworks; molecular dynamics; NMR spectroscopy;
D O I：
10.1002/anie.200603196
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Controlling guests: Porous coordination polymers containing mobile organic groups, such as naphthalene rings (see picture), are synthesized, and their rotational motion is characterized by solid-state 2H NMR spectroscopy. The rotation of the groups can be switched off (blue) by guest (blue spheres) adsorption and switched on (yellow) again by guest desorption. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7226 / 7230
页数：5
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