Synthesis and crystal structure of zinc coordination polymer with ferrocenedicarboxylic acid as ligand

被引:0
|
作者
Leng, SW [1 ]
Wu, G [1 ]
Xin, MH [1 ]
Tang, LL [1 ]
Zhu, GS [1 ]
Fan, Y [1 ]
Shi, SH [1 ]
机构
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
来源
关键词
coordination polymer; ferrocenedicarboxylic acid; crystal structure;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound [Zn (Py)(2)L](n) (L = 1, 2'-ferrocenedicarboxylate) was synthesized under mild conditions and its crystal structure was characterized. It crystallizes in a monoclinic system, space group C2/c with the cell parameters a=1. 683 0(5) nm, b=1. 380 4(3) nm, c=1. 746 2(3) nm, beta=108. 78 (2)degrees, V=3. 840 8(15) nm(3), Z=8, M-r=485. 52, T=293(2) K, D-c=3. 359 Mg/m(3), mu=4. 073 mm(-1), F(000)=3 872, R-1=0. 040 1, wR(2)=0. 113 2. The compound exhibits an unusual one-dimensional chain consisting of two zigzag chains.
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页码:817 / 819
页数:3
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