Benefits of very thin PCBM and LiF layers for solution-processed p-i-n perovskite solar cells

被引：625

作者：

Seo, Jangwon ^{[1
]}

Park, Sangman ^{[1
]}

Kim, Young Chan ^{[1
]}

Jeon, Nam Joong ^{[1
]}

Noh, Jun Hong ^{[1
]}

Yoon, Sung Cheol ^{[1
]}

Seok, Sang Il ^{[1
,2
]}

机构：

[1] Korea Res Inst Chem Technol, Div Adv Mat, Taejon 305600, South Korea

[2] Sungkyunkwan Univ, Dept Energy Sci, Suwon 440746, South Korea

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2014年 / 7卷 / 08期

基金：

新加坡国家研究基金会;

关键词：

HIGH-EFFICIENCY; LOW-COST; ELECTRON; PERFORMANCE; TRIHALIDE; LENGTHS; ROUTE;

D O I：

10.1039/c4ee01216j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly efficient p-i-n perovskite solar cells employing a flat and thick CH(3)NH(3)Pbl(3) film and a thin PCBM film are fabricated by the solution-process at low temperature. Through attainment of optimized PCBM thickness and insertion of the LW interlayer, the unit cell shows 14.1% of overall power conversion efficiency (PCE) with a J(sc) of 20.7 mA cm(-2), a V-oc of 0.866 V, and a FF of 78.3% under AM 1.5G 100 mW cm(-2) conditions, while a larger area 10 cell serially connected module (10 x 10 cm(2)) shows an 8.7% PCE. These PCE values are the highest reported to date for the planar perovskite-PCBM solar cells.

引用

页码：2642 / 2646

页数：5

共 50 条

[1] Solution-processed inorganic copper(I) thiocyanate (CuSCN) hole transporting layers for efficient p-i-n perovskite solar cells
Zhao, K.
Munir, R.
Yan, B.
Yang, Y.
Kim, T.
Amassian, A.
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (41) : 20554 - 20559
[2] p-i-n Structured Semitransparent Perovskite Solar Cells with Solution-Processed Electron Transport Layer
Guchhait, Asim
Dalapati, Goutam Kumar
Sonar, Prashant
Gopalan, Saianand
Bin Suhaimi, Firdaus
Das, Tapas
Dutt, V. G. Vasavi
Mishra, Nimai
Mahata, Chandreswar
Kumar, Avishek
Ramakrishna, Seeram
JOURNAL OF ELECTRONIC MATERIALS, 2021, 50 (10) : 5732 - 5739
[3] p-i-n Structured Semitransparent Perovskite Solar Cells with Solution-Processed Electron Transport Layer
Asim Guchhait
Goutam Kumar Dalapati
Prashant Sonar
Saianand Gopalan
Firdaus Bin Suhaimi
Tapas Das
V. G. Vasavi Dutt
Nimai Mishra
Chandreswar Mahata
Avishek Kumar
Seeram Ramakrishna
Journal of Electronic Materials, 2021, 50 : 5732 - 5739
[4] Phenethylammonium Halide Blend as an Efficient Interlayer in Solution-Processed Inverted Planar p-i-n Perovskite Solar Cells
Chakrabarti, Tanwistha
Kaarthik, Sai
Perumal, Ajay
ACS APPLIED ENERGY MATERIALS, 2025, 8 (05): : 2837 - 2844
[5] Enhanced performance of perovskite solar cells with solution-processed n-doping of the PCBM interlayer
Bae, Jun-Ho
Noh, Yong-Jin
Kang, Minji
Kim, Dong-Yu
Kim, Hyun-Bin
Oh, Seung-Hwan
Yun, Jin-Mun
Na, Seok-In
RSC ADVANCES, 2016, 6 (69) : 64962 - 64966
[6] Large Perovskite Grain Growth in Low-Temperature Solution-Processed Planar p-i-n Solar Cells by Sodium Addition
Bag, Santanu
Durstock, Michael F.
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (08) : 5053 - 5057
[7] Solution-processed perovskite solar cells
Chang, Jian-hui
Liu, Kun
Lin, Si-yuan
Yuan, Yong-bo
Zhou, Cong-hua
Yang, Jun-liang
JOURNAL OF CENTRAL SOUTH UNIVERSITY, 2020, 27 (04) : 1104 - 1133
[8] Biphenyl Triarylamine Hole Transport Material for Highly Efficient and Low-Temperature Solution-Processed p-i-n Perovskite Solar Cells
Meng, Juan
Song, Dandan
Xu, Zheng
Zhao, Suling
Qiao, Bo
Huang, Di
Li, Yang
Yuan, Binbin
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2018, 18 (11) : 7374 - 7379
[9] Efficient indoor p-i-n hybrid perovskite solar cells using low temperature solution processed NiO as hole extraction layers
Jagadamma, Lethy Krishnan
Blaszczyk, Oskar
Sajjad, Muhammad T.
Ruseckas, Arvydas
Samuel, Ifor D. W.
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2019, 201
[10] Cross-Linkable Fullerene Derivatives for Solution-Processed n-i-p Perovskite Solar Cells
Wojciechowski, Konrad
Ramirez, Ivan
Gorisse, Therese
Dautel, Olivier
Dasari, Raghunath
Sakai, Nobuya
Hardigree, Josue Martinez
Song, Seulki
Marder, Seth
Riede, Moritz
Wantz, Guillaume
Snaith, Henry J.
ACS ENERGY LETTERS, 2016, 1 (04): : 648 - 653

← 1 2 3 4 5 →