Tin Phosphide as a Promising Anode Material for Na-Ion Batteries

被引：374
|
作者：
Kim, Youngjin [1 ]
Kim, Yongil [2 ]
Choi, Aram [2 ]
Woo, Sangwon [2 ]
Mok, Duckgyun [2 ]
Choi, Nam-Soon [2 ]
Jung, Yoon Seok [2 ]
Ryu, Ji Heon [3 ]
Oh, Seung M. [1 ]
Lee, Kyu Tae [2 ]
机构：
[1] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151744, South Korea
[2] UNIST, Sch Energy & Chem Engn, Ulsan 689798, South Korea
[3] Korea Polytech Univ, Grad Sch Knowledge Based Technol & Energy, Gyeonggi 429793, South Korea
来源：
ADVANCED MATERIALS | 2014年 / 26卷 / 24期
基金：
新加坡国家研究基金会;
关键词：
sodium ion battery; tin phosphide; anode; reaction mechanism; electrochemical performance; NEGATIVE ELECTRODE MATERIAL; ELECTROCHEMICAL REACTIVITY; MECHANOCHEMICAL METHOD; HIGH-CAPACITY; SODIUM; STORAGE; COMPOSITE; MECHANISM; CU3P;
D O I：
10.1002/adma.201305638
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Sn4P3 is introduced for the first time as an anode material for Na-ion batteries. Sn4P3 delivers a high reversible capacity of 718 mA h g-1, and shows very stable cycle performance with negligible capacity fading over 100 cycles, which is attributed to the confinement effect of Sn nanocrystallites in the amorphous phosphorus matrix during cycling. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4139 / 4144
页数：6
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