Beyond copper-catalyzed azide-alkyne 1,3-dipolar cycloaddition: Synthesis and mechanism insights

被引：44
|
作者：
Gomes, Roberto S. [1 ,2 ]
Jardim, Guilherme A. M. [3 ]
de Carvalho, Renato L. [3 ]
Araujo, Maria H. [3 ]
da Silva Junior, Eufranio N. [3 ]
机构：
[1] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
[2] Fed Univ Grande Dourados, Fac Exact Sci & Technol, Dourados, MS, Brazil
[3] Univ Fed Minas Gerais, Dept Chem, Inst Exact Sci, BR-31270901 Belo Horizonte, MG, Brazil
来源：
TETRAHEDRON | 2019年 / 75卷 / 27期
关键词：
Click chemistry; Azide; Alkyne; CuAAC; Cycloaddition; HETEROCYCLIC CARBENE LIGANDS; CLICK CHEMISTRY; TERMINAL ALKYNES; 1,5-DISUBSTITUTED 1,2,3-TRIAZOLES; RUTHENIUM COMPLEXES; REACTIVITY; TRIAZOLES; METATHESIS; LIGATION;
D O I：
10.1016/j.tet.2019.05.046
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The current manuscript describes the catalysts in click chemistry reactions, mechanism insights and use of other metals beyond copper associated with Azide-Alkyne Cycloadditions (AAC). Due to their biological importance and several applications in various areas of science, significant efforts have been devoted to devise robust methods for the synthesis of triazoles. Among these approaches, azide-alkyne cycloadditions strategy has been consolidated as a powerful tool for preparing this class of heterocycles. Herein, click reactions involving catalysis with metals other than copper are presented and critically discussed. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3697 / 3712
页数：16
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