Hydrogen Production from Water Catalyzed by an Air-stable Di-iron Complex with a Bio-relevant Fe2(μ-S)2 Core

被引：13

作者：

Yamaguchi, Toshiki ^{[1
]}

Masaoka, Shigeyuki ^{[1
]}

Sakai, Ken ^{[1
]}

机构：

[1] Kyushu Univ, Fac Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan

来源：

CHEMISTRY LETTERS | 2009年 / 38卷 / 05期

关键词：

FE-ONLY HYDROGENASE; ACTIVE-SITE; IRON HYDROGENASE; EVOLUTION; ELECTROCHEMISTRY; CRYSTAL; MODELS;

D O I：

10.1246/cl.2009.434

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An air-stable dinuclear iron-dithiolene complex with an Fe-2(mu-S)(2) core, [Fe-III(mnt)(2)](2)(2-) (mnt = maleonitriledithiolate), has been found to serve as an electrode catalyst toward the reduction of water into molecular hydrogen with an overpotential of 560 mV. The acid form of a buffer reagent, such as CH3CO2H, has been found to serve as a major proton mediator during the electrocatalytic tic hydrogen evolution.

引用

页码：434 / 435

页数：2

共 14 条

[1] Water-soluble and air-stable [2Fe-2S]-metallopolymers: A new class of electrocatalysts for H2 production via water splitting
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[2] Acetonitrile activation in di-iron μ-carbyne complexes:: synthesis and structure of the cyanomethyl complex [Fe2(μ-CNMe2)(μ-CO)(CO)(CH2CN)(CP)2]
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1600, (ACS, Washington, DC, USA):
[5] The flexible Fe2(μ-O)2 diamond core:: A terminal iron(IV)-oxo species generated from the oxidation of a bis(μ-oxo)diiron(III) complex
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Wang, HT
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[7] Homogeneous photocatalytic production of hydrogen from water by a bioinspired [Fe2S2] catalyst with high turnover numbers
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[8] STEPWISE SYNTHESIS OF TROPONE FROM ETHYLENE AND CARBON-MONOXIDE AT A DI-IRON CENTER - CRYSTAL-STRUCTURE OF [FE2(CO)4(MU-C6H6CO)(MU-PH2PCH2PPH2)]
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[10] Generation of σ,π-furyl and thienyl ligands at di-iron centers via facile phosphorus-carbon bond cleavage: Synthesis and molecular structures of [Fe2(CO)6(μ-η1,η2-C4H3E){μ-P(C4H3E)2}] (E = O, S)
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