Solid-state spectroscopic properties of dinuclear cyclometalated Pt(II) complexes with different bridging ligands and anions

被引：7
|
作者：
Yang, Qian-Ying [1 ,2 ]
Zhang, Hua-Hong [1 ,2 ]
Xu, Guo [1 ,2 ]
Diao, Zi-Xuan [1 ,2 ]
Zhou, Zong-Mei [1 ,2 ]
Zhang, Da-Shuai [1 ,2 ]
Chen, Xin-Han [3 ]
Zhang, Xiao-Peng [1 ,2 ]
Shi, Zai-Feng [1 ,2 ]
机构：
[1] Hainan Normal Univ, Coll Chem & Chem Engn, Haikou 571158, Hainan, Peoples R China
[2] Key Lab Water Pollut Treatment & Resource Reuse H, Haikou 571158, Hainan, Peoples R China
[3] Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Key Lab Biomass Based Green Fuels & Chem, Nanjing 210037, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2021年 / 515卷
基金：
中国国家自然科学基金;
关键词：
Dinuclear cyclometalated Pt(II) complexes; Crystal structures; Luminescence; Mechanochromism; Vapochromism;
D O I：
10.1016/j.ica.2020.120072
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Crystal structures of dinuclear cyclometalated Pt(II) complexes with different bridging bis(diphenylphosphino) alkane ligands and counter anions have been compared, and solid-state emissions of crystallite powders and PMMA films doped with luminescent Pt(II) complexes have been investigated. Interestingly, mechanochromic and vapochromic properties are exhibited for solids of dinuclear cyclometalated Pt(II) complex (-)-1 bridged by bis(diphenylphosphino)methane (dppm), and multiple cycles have been repeated without any detectable degradation. However, no distinct stimuli-induced chromism can be observed with the naked eyes for solids of (-)-1 with other counter anions and PMMA films. In addition, with increasing the length of the bridging diphosphine ligand, green-solids without effective intramolecular Pt<bold>Pt contacts have been obtained</bold>, and mechanochromic and vapochromic phenomena could not be detected.
引用
收藏
页数：8
相关论文
共 50 条
  • [1] Syntheses, crystal structures, and solid-state spectroscopic properties of dinuclear cyclometallated platinum(II) complexes with mercaptobenzoazoles as bridging ligands
    Yamada, Yasunori
    Matsumoto, Reina
    Kori, Daishin
    Koikawa, Masayuki
    INORGANICA CHIMICA ACTA, 2021, 515
  • [2] DINUCLEAR PALLADIUM(II) COMPLEXES CONTAINING ANILIDE ANIONS AS BRIDGING LIGANDS
    OKEYA, S
    YOSHIMATSU, H
    NAKAMURA, Y
    KAWAGUCHI, S
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1982, 55 (02) : 483 - 491
  • [3] Variance of Solid-state Pt•••Pt Interactions in Luminescent Cyclometalated Cationic Pt(II)-isocyanide Complexes
    Qi Xiao-Wei
    Wu Shui-Xing
    Han Li-Zhi
    Shi Zai-Feng
    Zhang Xiao-Peng
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 39 (04) : 709 - 717
  • [4] The Influence of Cyclometalated Ligand Motifs on the Solid-State Assemblies and Luminescent Properties of Pt(II)-Tl(I) Complexes
    Paziresh, Sareh
    Sicilia, Violeta
    Ara, Irene
    Martin, Antonio
    Fuertes, Sara
    ORGANOMETALLICS, 2019, 38 (19) : 3804 - 3815
  • [5] Variance of Solid-state Pt···Pt Interactions in Luminescent Cyclometalated Cationic Pt(Ⅱ)-isocyanide Complexes
    祁晓炜
    吴水星
    韩立志
    史载锋
    张小朋
    Chinese Journal of Structural Chemistry, 2020, 39 (04) : 709 - 717
  • [6] DINUCLEAR COMPLEXES OF GOLD(I) CONTAINING BRIDGING CYCLOMETALATED ARYLPHOSPHANE OR ARYLARSANE LIGANDS
    BENNETT, MA
    BHARGAVA, SK
    GRIFFITHS, KD
    ROBERTSON, GB
    WICKRAMASINGHE, WA
    WILLIS, AC
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (03): : 258 - 260
  • [7] Dinuclear palladium(II) complexes with bridging amidate ligands
    Adrian, Rafael A.
    Zhu, Shourong
    Powell, Douglas R.
    Broker, Grant A.
    Tiekink, Edward R. T.
    Walmsley, Judith A.
    DALTON TRANSACTIONS, 2007, 39 (39) : 4399 - 4404
  • [8] Synthesis, Diastereomer Separation, and Optoelectronic and Structural Properties of Dinuclear Cyclometalated Iridium(III) Complexes with Bridging Diarylhydrazide Ligands
    Congrave, Daniel G.
    Hsu, Yu-ting
    Batsanov, Andrei S.
    Beeby, Andrew
    Bryce, Martin R.
    ORGANOMETALLICS, 2017, 36 (05) : 981 - 993
  • [9] Enhancement of the Photofunction of Phosphorescent Pt(II) Cyclometalated Complexes Driven by Substituents: Solid-State Luminescence and Circularly Polarized Luminescence
    Usuki, Tsukasa
    Uchida, Hikaru
    Omoto, Kenichiro
    Yamanoi, Yoshinori
    Yamada, Ayano
    Iwamura, Munetaka
    Nozaki, Koichi
    Nishihara, Hiroshi
    JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (17): : 10749 - 10756
  • [10] Half-lantern cyclometalated Pt(ii) and Pt(iii) complexes with bridging heterocyclic thiolate ligands: synthesis, structural characterization, and electrochemical and photophysical properties
    Shahsavari, Hamid R.
    Lalinde, Elena
    Moreno, M. Teresa
    Niazi, Maryam
    Kazemi, Sayed Habib
    Abedanzadeh, Sedigheh
    Barazandeh, Mohammad
    Halvagar, Mohammad Reza
    NEW JOURNAL OF CHEMISTRY, 2019, 43 (20) : 7716 - 7724
12345