Efficient synthesis of 6-mono-bromo-1,1′-bi-2-naphthol

被引：30
|
作者：
Cai, DW [1 ]
Larsen, RD [1 ]
Reider, PJ [1 ]
机构：
[1] Merck & Co Inc, Merck Sharp & Dohme Res Labs, Dept Proc Res, Rahway, NJ 07065 USA
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 22期
关键词：
6-mono-bromo-1,1 '-bi-2-naphthol; bromination;
D O I：
10.1016/S0040-4039(02)00730-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Through mono-ester formation of 1.1'-bi-2-naphthol (BINOL) with pivaloyl chloride the selective mono-bromination was achieved cleanly on the other ring to afford 6-mono-bromo-1,1'-bi-2-naphthol in an efficient 86% yield. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4055 / 4057
页数：3
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