Transition-Metal-Free C-N Bond Activation: Synthesis of α,α-Bis(arylthio) Aldehydes

被引：3
|
作者：
Gao, Xu-Hong [1 ]
Xu, Wei [1 ]
Zhang, Xing-Guo [1 ]
Deng, Chen-Liang [1 ]
机构：
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China
来源：
SYNLETT | 2017年 / 28卷 / 07期
基金：
中国国家自然科学基金;
关键词：
disulfides; transition-metal-free; alpha; alpha-bis(arylthio); aldehydes; tertiary amine; radicals; CARBON-NITROGEN BOND; TERTIARY-AMINES; COUPLING REACTIONS; CLEAVAGE; AMINATION; ALKENES; INDOLE; CATALYSIS; RADICALS; OXYGEN;
D O I：
10.1055/s-0036-1588135
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and convenient tandem reaction of I-2-catalzyed C-N bond activation of tertiary amines and subsequent aryl thiolation has been explored. A variety of disulfides and series of tertiary amines were efficiently converted into the corresponding alpha,alpha-bis(arylthio) aldehydes in moderate to good yields. The reaction proceeded well under transition-metal-free conditions via a C-N activation process.
引用
收藏
页码：841 / 846
页数：6
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