Structural, optical and electrochemical properties of SILAR-deposited zirconium-doped cadmium oxide thin films

被引:21
|
作者
Nkele, Agnes C. [1 ]
Nwanya, Assumpta C. [1 ,2 ,3 ]
Nwankwo, Nwankwo U. [1 ,4 ]
Ekwealor, A. B. C. [1 ]
Osuji, Rose U. [1 ,2 ,3 ]
Bucher, R. [2 ]
Maaza, Malik [2 ,3 ]
Ezema, Fabian, I [1 ,2 ,3 ,5 ]
机构
[1] Univ Nigeria Nsukka, Dept Phys & Astron, Nsukka, Nigeria
[2] iThemba Labs Natl Res Fdn, Nanosci African Network NANOAFNET, 1 Old Faure Rd,POB 722, ZA-7129 Somerset West, Western Cape Pr, South Africa
[3] Univ South Africa UNISA, Coll Grad Studies, UNESCO UNISA Africa Chair Nanosci Nanotechnol, Pretoria, South Africa
[4] Alex Ekwueme Fed Univ Ndufu Alike, Dept Phys Geol Geophys, Ikwo, Ebonyi State, Nigeria
[5] Coal City Univ, Fac Nat & Appl Sci, Dept Phys, Enugu, Nigeria
来源
MATERIALS RESEARCH EXPRESS | 2019年 / 6卷 / 09期
关键词
cadmium oxide; thin films; SILAR; Zr dopant percentages; optical properties; electrochemical properties; ELECTRICAL-PROPERTIES; PHYSICAL-PROPERTIES; OPTOELECTRONIC PROPERTIES; FACILE SYNTHESIS; TRITON X-100; CDO FILMS; CD(OH)(2); ZN; NANOSTRUCTURE; MORPHOLOGY;
D O I
10.1088/2053-1591/ab31f5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Cadmium oxide (CdO) thin films were successfully deposited and doped with zirconium via a low-cost successive ionic layer adsorption and reaction (SILAR) technique using the source materials: cadmium nitrate (cation) and hydrogen peroxide solution (anion) onglass and stainless steel substrates. The morphological, structural, optical and electrochemical properties of the undoped and zirconium-doped films were investigated. Scanning electron microscope (SEM) images showed granular films and decreasing grain sizes with increasing dopant percentages. X-ray diffraction (XRD) patterns revealed a cubic crystal structure of the films while optical analyses showed good optical properties of the films with reduced bandgap energy ranging from 2.07 eV to 2.10 eV after annealing. Electrochemical studies showed good electrochemical features of the annealed undoped and 2% doped cadmium oxide films. The deposited films find application in optoelectronic devices.
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页数:12
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