Hitherto unknown eight-connected frameworks formed from A4B4O12 metal organophosphate heterocubanes

被引：7

作者：

Sharma, Kamna ^{[1
]}

Gupta, Sandeep K. ^{[1
]}

Borah, Aditya ^{[1
]}

Murugavel, Ramaswamy ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 55期

关键词：

ORGANIC FRAMEWORK; TRANSFORMATIONS; CRYSTALLINE; PHOSPHATES; COMPLEXES; DISCRETE; PLATFORM; DESIGN;

D O I：

10.1039/c9cc01893j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Modulation of a functional group on the distal part of a phosphate ester has been prudently exploited to selectively switch between the formation of D4R SBUs and 3-D framework structures. While amino substitution at the para-position of an aryl phosphate results in the isolation of tetra-amino functionalized discrete D4R zinc phosphate or its 4-connected 3-D framework, the introduction of an acetylamino substituent leads to a single-step assembly of a rare eight-connected 3-D framework solid.

引用

页码：7994 / 7997

页数：4

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