Optimization of the Mass Yield in the Biodiesel Production from Chicken Viscera Oil

被引:0
|
作者
Mazatto, Amanda Caroline Fernandes [1 ]
da Silva, Geovane Aparecido Ramos [1 ]
dos Santos, Patricia Daniele Silva [1 ]
Senes, Carlos Eduardo Rubio [1 ]
Visentainer, Jesui Vergilio [1 ]
Oliveira Santos, Oscar [1 ]
机构
[1] State Univ Maringa UEM, Dept Chem, Maringa, Parana, Brazil
关键词
Biodiesel; Gas chromatography; Response surface; Fatty Acids; SOYBEAN OIL; TRANSESTERIFICATION; FAT; METHODOLOGY; DIESEL;
D O I
10.1002/aocs.12437
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This work proposes the conversion of chicken viscera oil into biodiesel through the transesterification reaction using basic catalysis. For this, the properties of the raw material and the interferences of the variables on the mass yield of the chemical procedure were evaluated, such as reaction temperature (50-90 degrees C), catalyst concentration (0.5-2.5% m/m), oil: alcohol molar ratio (1:3 to 1:15) and reaction time (15-75 min).Through the execution of an experimental design procedure and subsequent application of the response surface methodology it was possible to maximize the yield of the transesterification reaction to 87.41% w/w, using the following experimental conditions: reaction temperature 70 degrees C, catalyst concentration 1% m/m, molar ratio 1:9, and reaction time 30 min. This result provides a reduction of 200% in the percentage of the catalyst used, 67% in the volume of alcohol, and 700% in the reaction time when compared to works using similar raw material published in the literature. Besides, the quality of the biodiesel produced was verified and is following the standards required by ASTM D6751 and EN 14214.
引用
收藏
页码:31 / 41
页数:11
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