Synthesis by-products from the Wacker oxidation of safrole in methanol using ρ-benzoquinone and palladium chloride

被引：15
|
作者：
Cox, M.
Klass, G.
机构：
[1] Forens Sci S Australia, Adelaide, SA 5000, Australia
[2] Univ S Australia, Adelaide, SA 5000, Australia
来源：
FORENSIC SCIENCE INTERNATIONAL | 2006年 / 164卷 / 2-3期
关键词：
safrole; MDP2P; 3,4-methylenedioxymethamphetamine; by-products; Wacker oxidation;
D O I：
10.1016/j.forsciint.2005.12.019
中图分类号：
DF [法律]; D9 [法律]; R [医药、卫生];
学科分类号：
0301 ; 10 ;
摘要：
This paper reports the identification of a number of by-products, which are produced during the Wacker oxidation of safrole to 3,4-methylenedioxyphenyl-2-propanone (MDP2P) using p-benzoquinone and palladium chloride when methanol is utilised as the solvent. Also described is the retrieval of these compounds from illicit samples from a clandestine laboratory, which was uncovered in South Australia in September 2003. (c) 2005 Elsevier Ireland Ltd. All rights reserved.
引用
收藏
页码：138 / 147
页数：10
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