Immediate and efficient oxidative deprotection of dithioacetals to carbonyl compounds by zinc dichromate trihydrate (ZnCr2O7•3H2O)

被引:7
|
作者
Firouzabadi, H [1 ]
Iranpoor, N [1 ]
Hassani, H [1 ]
Sobhani, S [1 ]
机构
[1] Shiraz Univ, Dept Chem, Coll Sci, Shiraz 71454, Iran
关键词
zinc dichromate trihydrate; oxidative deprotection; 1,3-dithianes; 1,3-dithiolanes; dibutyl dithioacetals; thioacetals; carbonyl compounds;
D O I
10.1081/SCC-120037908
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Zinc dichromate trihydrate (ZnCr2O7.3H(2)O) is an efficient oxidizing agent for the immediate deprotection of 1,3-dithianes, 1,3-dithiolanes, and dibutyl dithioacetals to their corresponding carbonyl compounds in non-aqueous and aprotic conditions at room temperature.
引用
收藏
页码:1967 / 1972
页数:6
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