Oxygenates synthesis from 1-hexene and syngas over supported cobalt catalysts

被引：7
|
作者：
Qiu, XQ [1 ]
Tsubaki, N
Fujimoto, K
Zhu, QA
机构：
[1] Tsing Hua Univ, State Key Lab C1 Chem & Technol, Dept Chem, Beijing 100084, Peoples R China
[2] Toyama Univ, Dept Mat Syst & Life Sci, Sch Engn, Toyama 9308555, Japan
[3] Univ Kitakyushu, Sch Environm Engn, Fukuoka 8080135, Japan
来源：
FUEL PROCESSING TECHNOLOGY | 2004年 / 85卷 / 8-10期
关键词：
oxygenate fuel; heterogeneous hydroformylation; 1-hexene; supported cobalt catalyst; solvent effect;
D O I：
10.1016/j.fuproc.2003.11.042
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The supported cobalt catalyst, such as CO/SiO2, was found to be very active and selective for the synthesis of oxygenates (alcohols and aldehydes) from syngas and 1-hexene under mild reaction conditions. The addition of methanol or ethanol to the reaction system could greatly improve the catalytic activity. Esters and ethers were produced in this reaction system. The methanol and ethanol could act not only as solvent but also as reactant to react with the produced heptanal, resulting the great increasing of 1-hexene conversion. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：1193 / 1200
页数：8
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