Transforming polyethylenimine into a pH-switchable hydrogel by additional supramolecular interactions

被引:24
|
作者
Fleischer, M. [1 ]
Schmuck, C. [1 ]
机构
[1] Univ Duisburg Essen, Inst Organ Chem, D-45141 Essen, Germany
关键词
CHEMISTRY; POLYMERS; GENE;
D O I
10.1039/c4cc03281k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Attaching a self-complementary zwitterionic supramolecular binding site to the amino groups of polyethyleneimine leads to a pH switchable hydrogel as dimerization of the zwitterions introduces additional crosslinks between the polymer chains. This gel responds to both the addition of either acid or base, as only the zwitterion can self-assemble but neither the protonated or deprotonated form.
引用
收藏
页码:10464 / 10467
页数:4
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