Performance enhancement of CsPbI2Br perovskite solar cells via stoichiometric control and interface engineering

被引:9
|
作者
Fatima, Kalsoom [1 ,2 ,3 ]
Haider, Muhammad Irfan [1 ,2 ]
Fakharuddin, Azhar [3 ]
Akhter, Zareen [2 ]
Sultan, Muhammad [1 ]
Schmidt-Mende, Lukas [3 ]
机构
[1] Quaid I Azam Univ Campus, Natl Ctr Phys, Nanosc & Technol Dept, Islamabad 44000, Pakistan
[2] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan
[3] Univ Konstanz, Dept Phys, D-78457 Constance, Germany
关键词
Non-stoichiometric; Perovskite solar cell; Stability; Charge transport layer; Interfacial modification; LEAD HALIDE PEROVSKITES; IMPROVED STABILITY; LIGHT; DEGRADATION; EFFICIENCY; HYBRID; IMPACT;
D O I
10.1016/j.solener.2020.10.007
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Caesium based inorganic halide perovskite are promising alternatives to address the degradation issue of the organic-inorganic hybrid halide perovskites. However, high iodine content in these inorganic perovskites leads to structural instability upon exposure to moisture. In this work, the stoichiometry of CsPbI2Br perovskite is slightly tuned and its effect on structural stability and device performance is studied. Afterward, the charge transport layers are optimized to improve the charge extraction in perovskite solar cells. Finally, the device performance is further improved via interfacial modification. The optimized device yielded a power conversion efficiency (PCE) of 9.7%.
引用
收藏
页码:654 / 660
页数:7
相关论文
共 50 条
  • [1] Boosting the performance of low-temperature processed CsPbI2Br planar perovskite solar cells by interface engineering
    Zhang, Xiang
    Yang, Jiajun
    Xie, Lai
    Lu, Xubing
    Gao, Xingsen
    Gao, Jinwei
    Shui, Lingling
    Wu, Sujuan
    Liu, Jun-Ming
    DYES AND PIGMENTS, 2021, 186
  • [2] Highly crystalline CsPbI2Br films for efficient perovskite solar cells via compositional engineering
    He, Fang
    Xu, Wenzhan
    Zhang, Meng
    Zhang, Xuan
    Ding, Baofu
    Wei, Guodan
    Kang, Feiyu
    RSC ADVANCES, 2019, 9 (52) : 30534 - 30540
  • [3] Interface optimization of CsPbI2Br based perovskite solar cells by device simulation
    Dong, Yujing
    Duan, Junjie
    Luo, Dengshuai
    Liu, Jiajun
    Wang, Xiaohui
    Liu, Xu
    Huang, Zhihao
    Li, Xuxiang
    Gao, Yanli
    MATERIALS TODAY COMMUNICATIONS, 2024, 39
  • [4] A silazane additive for CsPbI2Br perovskite solar cells
    Cao, Ruiqi
    Yue, Yaochang
    Zhang, Hong
    Cheng, Qian
    Wang, Boxin
    Li, Shilin
    Zhang, Yuan
    Li, Shuhong
    Zhou, Huiqiong
    CHINESE PHYSICS B, 2022, 31 (11)
  • [5] Interface Engineering for All-Inorganic CsPbI2Br Perovskite Solar Cells with Efficiency over 14%
    Yan, Lei
    Xue, Qifan
    Liu, Meiyue
    Zhu, Zonglong
    Tian, Jingjing
    Li, Zhenchao
    Chen, Zhen
    Chen, Ziming
    Yan, He
    Yip, Hin-Lap
    Cao, Yong
    ADVANCED MATERIALS, 2018, 30 (33)
  • [6] The progress and efficiency of CsPbI2Br perovskite solar cells
    Liu, Xin
    Li, Jie
    Cui, Xumei
    Wang, Xiao
    Yang, Dingyu
    JOURNAL OF MATERIALS CHEMISTRY C, 2023, 11 (02) : 426 - 455
  • [7] A silazane additive for CsPbI2Br perovskite solar cells
    曹瑞琪
    乐耀昌
    张弘
    程倩
    王博欣
    李世麟
    张渊
    李书宏
    周惠琼
    Chinese Physics B, 2022, 31 (11) : 70 - 75
  • [8] Minimizing Open-Circuit voltage deficit via interface engineering for highly efficient CsPbI2Br perovskite solar cells
    Li, Jing
    Yang, Jianming
    Ma, Junjie
    Liang, Jiwei
    Liu, Yongjie
    Hu, Xuzhi
    Chen, Cong
    Yang, Wenyan
    Min, Jie
    Bao, Qinye
    Fang, Guojia
    Tao, Chen
    CHEMICAL ENGINEERING JOURNAL, 2021, 417
  • [9] Control of CsPbI2Br Perovskite Colloidal Dispersion with 4-Methoxybenzenethiol for Slow Nucleation in CsPbI2Br Perovskite and Enhanced Solar Cell Performance
    Wang, Dongsheng
    Liu, Hanqing
    Wang, Guiqiang
    Meng, Fanning
    ACS APPLIED NANO MATERIALS, 2024, 7 (14) : 16162 - 16171
  • [10] Band engineering at the interface of all-inorganic CsPbI2Br solar cells
    Zhuang, Jing
    Wei, Yuanzhi
    Luan, Yigang
    Chen, Ningli
    Mao, Peng
    Cao, Shaokui
    Wang, Jizheng
    NANOSCALE, 2019, 11 (31) : 14553 - 14560