3D Scaffolded Nickel-Tin Li-Ion Anodes with Enhanced Cyclability

被引：86
|
作者：
Zhang, Huigang [1 ,2 ,3 ]
Shi, Tan [2 ,3 ]
Wetzel, David J. [3 ,4 ]
Nuzzo, Ralph G. [3 ,5 ]
Braun, Paul V. [3 ,5 ]
机构：
[1] Nanjing Univ, Coll Engn & Appl Sci, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China
[2] Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA
[3] Univ Illinois, Mat Res Lab, Urbana, IL 61801 USA
[4] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
[5] Univ Illinois, Dept Chem, Dept Mat Sci & Engn, Urbana, IL 61801 USA
来源：
ADVANCED MATERIALS | 2016年 / 28卷 / 04期
关键词：
HIGH-PERFORMANCE ANODE; LITHIUM STORAGE PERFORMANCE; HOLLOW CARBON SPHERES; HIGH-CAPACITY; ALLOY ELECTRODES; INTERMETALLIC ELECTRODES; NANOSTRUCTURED MATERIALS; NEGATIVE ELECTRODES; THIN-FILM; SN;
D O I：
10.1002/adma.201504780
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A 3D mechanically stable scaffold is shown to accommodate the volume change of a high-specific-capacity nickeltin nanocomposite during operation as a Li-ion battery anode. The nickel-tin anode is supported by an electrochemically inactive conductive scaffold with an engineered free volume and controlled characteristic dimensions, which engender the electrode with significantly improved cyclability.
引用
收藏
页码：742 / 747
页数：6
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