Copper(II) Complex Based on 3-Methyl-4-(4-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole

被引：0

作者：

Wang Zuo-Xiang ^{[1
]}

Gong Xiao-Ning ^{[1
]}

Qu Zhi-Rong ^{[1
]}

Wu Ping-Feng ^{[1
]}

Zhang Xiao-Ming ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 210096, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 25卷 / 03期

关键词：

copper(II) complex; crystal structure; fluorescence; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; DESIGN; 1,2,4-TRIAZOLE; TRINUCLEAR; CHEMISTRY; DERIVATIVES; TRIAZOLE; CORE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A copper(II) complex [CuL(H2O)(Sal)]center dot 0.5H(2)O was obtained by the reaction of copper(II) salicylate with 3-methyl-4-(4-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole (L) in ethanol-water solution at room temperature. The crystal belongs to triclinic system with space group P (1) over bar, and a=0.913 6(4) nm, b=1.122 2(5) nm, c=1.263 3 (7) nm, alpha=67.10(2)degrees, beta=76.37(3)degrees, gamma=68.17(2)degrees, V=1.101(1) nm(3), Z=2. The final refinement gave R-1=0.039 8 and omega R-2=0.106 0 for 3 453 reflections with I>2 sigma(I). This complex is a good purple fluorescent material in solid state at room temperature. CCDC: 685713.

引用

页码：567 / 570

页数：4

共 29 条

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