Radiation-initiated synthesis of tetrafluoroethylene telomers in 1,2-dibromotetrafluoroethane at a constant pressure of the monomer in the reactor

被引：2
|
作者：
Kichigina, G. A. [1 ]
Bol'shakov, A. I. [1 ]
Kushch, P. P. [1 ]
Kiryukhin, D. P. [1 ]
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
来源：
RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2014年 / 87卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
CHEMICAL-SYNTHESIS; TELOMERIZATION;
D O I：
10.1134/S10704272140400211
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The kinetics of radiation-initiated telomerization of tetrafluoroethylene in a 1,2-dibromotetrafluoroethane solution at a constant concentration (pressure) of the monomer in the reactor was studied. The properties, molecular structure, and morphology of the telomers were studied by IR spectroscopy, scanning electron microscopy, and elemental and thermal gravimetric analyses. The synthesized telomers show promise for the development of fluoropolymeric nanocomposites and protective hydrophobic and antifriction coatings.
引用
收藏
页码：518 / 524
页数：7
相关论文
共 21 条
  • [1] Radiation-initiated synthesis of tetrafluoroethylene telomers in 1,2-dibromotetrafluoroethane at a constant pressure of the monomer in the reactor
    G. A. Kichigina
    A. I. Bol’shakov
    P. P. Kushch
    D. P. Kiryukhin
    Russian Journal of Applied Chemistry, 2014, 87 : 518 - 524
  • [2] Radiation-initiated telomerization of tetrafluoroethylene in 1,2-dibromotetrafluoroethane
    G. A. Kichigina
    P. P. Kusch
    A. I. Bolshakov
    D. P. Kiryukhin
    V. M. Buznik
    High Energy Chemistry, 2012, 46 : 143 - 147
  • [3] Radiation-initiated telomerization of tetrafluoroethylene in 1,2-dibromotetrafluoroethane
    Kichigina, G. A.
    Kusch, P. P.
    Bolshakov, A. I.
    Kiryukhin, D. P.
    Buznik, V. M.
    HIGH ENERGY CHEMISTRY, 2012, 46 (03) : 143 - 147
  • [4] Radiation-initiated telomerization of tetrafluoroethylene in acetone at a constant monomer concentration
    A. I. Bol’shakov
    G. A. Kichigina
    A. M. Kolesnikova
    D. P. Kiryukhin
    Russian Journal of Applied Chemistry, 2011, 84 : 691 - 695
  • [5] 1,2-DIBROMOTETRAFLUOROETHANE AS AN INITIATOR FOR PHOTOPOLYMERIZATION OF TETRAFLUOROETHYLENE
    MUNGALL, WS
    MARTIN, CL
    BORGESON, GC
    MACROMOLECULES, 1975, 8 (06) : 934 - 935
  • [6] Radiation-initiated telomerization of tetrafluoroethylene in acetone at a constant monomer concentration
    Bol'shakov, A. I.
    Kichigina, G. A.
    Kolesnikova, A. M.
    Kiryukhin, D. P.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2011, 84 (04) : 691 - 695
  • [7] Tetrafluoroethylene telomers: Radiation-initiated chemical synthesis, properties, and application prospects
    Kiryukhin, D. P.
    Kichigina, G. A.
    Bouznik, V. M.
    POLYMER SCIENCE SERIES A, 2013, 55 (11) : 631 - 642
  • [8] Tetrafluoroethylene telomers: Radiation-initiated chemical synthesis, properties, and application prospects
    D. P. Kiryukhin
    G. A. Kichigina
    V. M. Bouznik
    Polymer Science Series A, 2013, 55 : 631 - 642
  • [9] Tetrafluoroethylene telomers with reactive end groups: radiation-initiated synthesis, properties, and prospects for applications
    Kichigina, G. A.
    Kushch, P. P.
    Kiryukhin, D. P.
    RUSSIAN CHEMICAL BULLETIN, 2021, 70 (09) : 1640 - 1650
  • [10] Radiation-Initiated Synthesis of Tetrafluoroethylene Telomers with Terminal Hydroxy Groups and Controllable Chain Length
    G. A. Kichigina
    P. P. Kushch
    D. P. Kiryukhin
    Russian Journal of Applied Chemistry, 2018, 91 : 1018 - 1024
123