New chiral cobalt salen complexes containing Lewis acid BF3;: a highly reactive and enantioselective catalyst for the hydrolytic kinetic resolution of epoxides

被引：51

作者：

Shin, CK

Kim, SJ

Kim, GJ ^{[1
]}

机构：

[1] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea

[2] RStech Corp, Taejon 306230, South Korea

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 40期

关键词：

chiral cobalt salen; Lewis acid; BF3; resolution; epoxide;

D O I：

10.1016/j.tetlet.2004.08.067

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new type of chiral cobalt salen complexes bearing BF3 Lewis acid proved to be reactive and enantioselective in the hydrolytic resolution of terminal epoxides. The polymer type salen catalysts also showed a high enantioselectivity in the same reaction. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：7429 / 7433

页数：5

共 38 条

[1] Chiral cobalt salen complexes containing Lewis acid: A highly reactive and enantioselective catalyst for the hydrolytic kinetic resolution of terminal epoxides
Jiang, C. J.
Chen, Z. R.
[J]. KINETICS AND CATALYSIS, 2008, 49 (04) : 474 - 478
[2] Chiral cobalt salen complexes containing Lewis acid: A highly reactive and enantioselective catalyst for the hydrolytic kinetic resolution of terminal epoxides
C. J. Jiang
Z. R. Chen
[J]. Kinetics and Catalysis, 2008, 49 : 474 - 478
[3] Novel polymeric and oligomeric Co(salen) complexes as highly reactive and enantioselective catalysts for the hydrolytic kinetic resolution of epoxides
Zheng, Xiaolai
Jones, Christopher W.
Weck, Marcus
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
[4] Enantioselective Hydrolytic Kinetic Resolution of Epoxides Catalyzed by Chiral Co(III) Salen Complexes Immobilized in the Membrane Reactor
Sung-Dae Choi
Geon-Joong Kim
[J]. Catalysis Letters, 2004, 92 : 35 - 40
[5] Enantioselective hydrolytic kinetic resolution of epoxides catalyzed by chiral Co(III) salen complexes immobilized in the membrane reactor
Choi, SD
Kim, GJ
[J]. CATALYSIS LETTERS, 2004, 92 (1-2) : 35 - 40
[6] Continuous enantioselective kinetic resolution of terminal epoxides using immobilized chiral cobalt-salen complexes
Solodenko, Wladimir
Jas, Gerhard
Kunz, Ulrich
Kirschning, Andreas
[J]. SYNTHESIS-STUTTGART, 2007, 4 (04): : 583 - 589
[7] Chiral calix-salen cobalt complexes, catalysts for the enantioselective dynamic hydrolytic kinetic resolution of epibromohydrin
Dandachi, Hiba
Nasrallah, Houssein
Ibrahim, Farah
Hong, Xiang
Mellah, Mohamed
Jaber, Nada
Schulz, Emmanuelle
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 395 : 457 - 462
[8] Enantioselective Hydrolytic Kinetic Resolution of 1,2-epoxy-3-phenoxy Propane Derivatives by New Chiral (Salen) Cobalt Complexes
Santosh Singh Thakur
Wenji Li
Chang-Kyo Shin
Geon-Joong Kim
[J]. Catalysis Letters, 2005, 104 : 151 - 156
[9] Synthesis of polymeric salen complexes and application in the enantioselective hydrolytic kinetic resolution of epoxides as catalysts
Kwon, MA
Kim, GJ
[J]. CATALYSIS TODAY, 2003, 87 (1-4) : 145 - 151
[10] Enantioselective hydrolytic kinetic resolution of 1,2-epoxy-3-phenoxy propane derivatives by new chiral (Salen) cobalt complexes
Thakur, SS
Li, WJ
Shin, CK
Kim, GJ
[J]. CATALYSIS LETTERS, 2005, 104 (3-4) : 151 - 156

← 1 2 3 4 →