Palladium-Promoted Carbon-Nitrogen Bond Cleavage in 1,3,5-Triazinane Derivatives

被引：2

作者：

Murinov, Yu. I. ^{[1
]}

Golubyatnikova, L. G. ^{[1
]}

Khisamutdinov, R. A. ^{[1
]}

Badamshin, A. G. ^{[1
]}

Dokichev, V. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Ufa Fed Res Ctr, Ufa Inst Chem, Ufa 450054, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2020年 / 90卷 / 11期

关键词：

1; 3; 5-triazinane; amino acid esters; palladium complexes; AMINO-ACIDS; C-N; COMPLEXES;

D O I：

10.1134/S1070363220110055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

trans-Dichloropalladium(II) complexes with amino acid esters PdCl2L2 have been synthesized via selective hydrolytic cleavage of the nitrogen-carbon bond in 1,3,5-tris(ethoxycarbonylmethyl)- and 1,3,5-tris[(S)-1 '(methoxycarbonyl)ethyl]-1,3,5-triazinane under the action of palladium(II) in methanol or in water-acetone mixture. The nucleophilic attack of water or methanol results in selective cleavage of the 1,3,5-triazinane ring in the complexes of palladium(II) with the starting triazinanes, affording the dichloropalladium(II) complexes with amino acids esters.

引用

页码：2048 / 2052

页数：5

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