Thermally activated polymorphic transition from a 1D ribbon to a 2D carpet: squaric acid on Au(111)

被引：8

作者：

Ueji, Kan ^{[1
,2
]}

Jung, Jaehoon ^{[1
]}

Oh, Junepyo ^{[1
]}

Miyamura, Kazuo ^{[2
]}

Kim, Yousoo ^{[1
]}

机构：

[1] RIKEN, Surface & Interface Sci Lab, Wako, Saitama 3510198, Japan

[2] Tokyo Univ Sci, Fac Sci, Dept Chem, Tokyo 1628601, Japan

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 76期

关键词：

REVERSIBLE PHASE-TRANSITIONS; SURFACE; ASSEMBLIES; LAYERS;

D O I：

10.1039/c4cc05794e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polymorphic transition from the 1D ribbon to the 2D carpet superstructure of squaric acid molecules on Au(111) was achieved through a thermally activated process. Our combined STM and DFT study revealed that the molecular arrangements in 1D and 2D superstructures are determined by the stability of their conformational isomers and assembled structures, respectively.

引用

页码：11230 / 11233

页数：4

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