A novel synthesis of avermectin B1a from avermectin B2a

被引：3

作者：

Katoh, T ^{[1
]}

Itoh, E ^{[1
]}

Terashima, S ^{[1
]}

机构：

[1] Sagami Chem Res Ctr, Kanagawa 2290012, Japan

来源：

HETEROCYCLES | 2000年 / 52卷 / 02期

关键词：

D O I：

10.3987/COM-99-S107

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title synthesis was achieved via a four-step sequence of reactions including selective silylation of the C4 "- and the C5-hydroxy groups, mesylation of the remaining C23-hydroxy group, tetra-n-butylammonium oxalate-induced elimination, and deprotection of the silyl protecting groups.

引用

页码：587 / 590

页数：4

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