New clathrate hydrate structure: High-pressure tetrahydrofuran hydrate with one type of cavity

被引：22
|
作者：
Kurnosov, AV
Komarov, VY
Voronin, VI
Teplykh, AE
Manakov, AY
机构：
[1] AV Nikolaev Inst Inorgan Chem SD RAS, Novosibirsk 630090, Russia
[2] Russian Acad Sci, Inst Met Phys UrD, Ekaterinburg 620219, Russia
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 22期
关键词：
clathrates; high-pressure chemistry; host-guest systems; hydrates; neutron diffraction;
D O I：
10.1002/anie.200453712
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Water cages: A water framework consisting of uniform space-filling polyhedral cages containing tetrahydrofuran molecules has been detected in a new clathrate hydrate formed under a pressure of 0.8 GPa. Topologically the cage represents a space-filling tetradecahedron with four tetra-, four penta-, and six hexagonal faces (see picture).
引用
收藏
页码：2922 / 2924
页数：3
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