Synthesis and evaluation of spectroscopic properties of newly synthesized push-pull 6-amino-8-styryl purines

被引:17
|
作者
Vabre, Roxane [1 ,2 ]
Legraverend, Michel [2 ]
Piguel, Sandrine [1 ,2 ]
机构
[1] Univ Paris 11, F-91405 Orsay, France
[2] Ctr Univ Orsay, Inst Curie CNRS, UMR 176, F-91405 Orsay, France
关键词
Styrylpurines; Push-pull; Fluorescence; Solvatochromy; Direct C-H bond functionalization; Heterocyclic chemistry; VIOLET ELECTROLUMINESCENCE; PHOTOPHYSICAL PROPERTIES; FLUORESCENT; ALKENYLATION; NUCLEOSIDES; PROBE; DNA;
D O I
10.1016/j.dyepig.2014.01.025
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
New 6-amino-8-styryl purines were synthesized using direct C H bond functionalization. These push pull compounds showed strong fluorescence, high quantum yields and a noteworthy fluorosolvatochromism. Deprotected purines 7a-c are promising targets for incorporation into nucleic acids as they are still fluorescent in aqueous media. (c) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:145 / 151
页数:7
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