Synthesis, Characterization and Photocatalysis of Mesoporous TiO2

被引:3
|
作者
Zhang, Xiangchao [1 ,2 ]
Jia, Yanrong [2 ]
Yu, Qumin [1 ]
Tang, Aidong [2 ]
Zhang, Shiying [1 ]
机构
[1] Changsha Univ, Key Lab Applicat Technol Environm Photocatalysis, Changsha 410003, Hunan, Peoples R China
[2] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Mesoporous TiO2; Evaporation induced self; assembly; Photocatalysis; Formaldehyde; CHEMISTRY; WATER;
D O I
10.14233/ajchem.2014.18140
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The mesoporous TiO2 nanoparticulate has been prepared by evaporation induced self-assembly method using EO-PO type polyether P123 as a template. The small angle X-ray diffraction, wide angle X-ray diffraction, high-resolution transmission electron microscopy and N2 isothermal adsorption-desorption are used to study the microstructure and morphology of the as-synthesized mesoporous TiO2. The results demonstrate that the mesoporous TiO2 belongs to anatase and the size is 20-30 nm. The sample is prepared using P123 as a template with average pore size distribution of 11.54 nm, specific surface area of 84.83 m(2)/g and pore volume of 0.234 cm(3)/g. The assynthesized mesoporous TiO2 exhibits remarkably high photocatalytic activity of 93.6 % in decomposing formaldehyde under ultraviolet light irradiations for 90 min. This work provides a basic experimental process for the preparation of mesoporous TiO2, which will possess a broad prospect in terms of the applications in improving indoor air quality.
引用
收藏
页码:5491 / 5494
页数:4
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