Reactivity of neodymium and samarium nitrides

被引：2

作者：

Kuzyaev, Dmitry M. ^{[1
]}

Maleev, Alexander A. ^{[1
]}

Kulikova, Tatyana I. ^{[1
]}

Vorozhtsov, Dmitry L. ^{[2
]}

Bochkarev, Mikhail N. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Tropinin Str 49, Nizhnii Novgorod 603950, Russia

[2] Nizhny Novgorod NI Lobachevsky State Univ, Gagarin Ave 23, Nizhnii Novgorod 603950, Russia

来源：

JOURNAL OF CHEMICAL RESEARCH | 2017年 / 02期

基金：

俄罗斯科学基金会;

关键词：

Nd; Sm; nitrides; iodine; reactivity; sulfur; C6F5OH; CpH; ARYLOXIDE; YTTRIUM; COMPLEXES; DIVALENT; SCANDIUM;

D O I：

10.3184/174751917X14839766277332

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of NdN and SmN with iodine gave the iodide-nitrides (NdI2)(3)N(DME)(4) and (SmI)(3)N-2(THF)(2), which are inert towards sulfur, in contrast to the neodymium and dysprosium iodide-nitrides prepared by the reaction of LnI(2) with N-2. Reaction of NdN and SmN with C6F5OH and CpH gave the organolanthanide derivatives Ln( C5F5O)(3)(THF)(n)(Ln = Nd or Sm) and Cp3Sm with moderate and low yields, respectively. Phenylacetylene and styrene do not react with SmN.

引用

页码：82 / 84

页数：3

共 50 条

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