Effect of ZrO2 morphology in copper-cerium-zirconium oxide systems on their catalytic properties in the reaction of co oxidation in hydrogen-rich mixtures

被引：7

作者：

Gural'skii, A. V. ^{[1
]}

Pakharukova, V. P. ^{[2
]}

Kosmambetova, G. R. ^{[1
]}

Strizhak, P. E. ^{[1
]}

Moroz, E. M. ^{[2
]}

Gritsenko, V. I. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, LV Pisarzhevsky Phys Chem Inst, UA-03028 Kiev, Ukraine

[2] Russian Acad Sci, GK Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia

来源：

THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2009年 / 45卷 / 02期

关键词：

selective oxidation of CO in a stream of hydrogen; nanosized zirconium dioxide; copper-cerium-zirconium catalysts;

D O I：

10.1007/s11237-009-9074-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We studied the catalytic properties of copper-cerium oxide systems, deposited on supports obtained by calcination of yttrium-stabilized zirconium dioxide at 300-1000 A degrees C, in the reaction of selective oxidation of CO in a stream of hydrogen. We have shown that the catalytic activity of the samples obtained correlates with the activity of the original supports in the reaction of CO oxidation: the highest CO conversion is observed on catalysts with the highest and the lowest specific surface area.

引用

页码：125 / 130

页数：6

共 17 条

[1] Effect of ZrO2 morphology in copper–cerium–zirconium oxide systems on their catalytic properties in the reaction of co oxidation in hydrogen-rich mixtures
A. V. Gural’skii
V. P. Pakharukova
G. R. Kosmambetova
P. E. Strizhak
É. M. Moroz
V. I. Gritsenko
Theoretical and Experimental Chemistry, 2009, 45 : 125 - 130
[2] Effect of the nature of the support for copper-cerium oxide catalysts on selective oxidation of CO in hydrogen-rich mixtures
Kosmambetova G.R.
Gritsenko V.I.
Strizhak P.E.
Korduban A.M.
Theoretical and Experimental Chemistry, 2006, 42 (2) : 133 - 138
[3] Selective catalytic methanation of CO in hydrogen-rich gases over Ni/ZrO2 catalyst
Liu, Qihai
Dong, Xinfa
Mo, Xinman
Lin, Weiming
JOURNAL OF NATURAL GAS CHEMISTRY, 2008, 17 (03): : 268 - 272
[4] Selective catalytic methanation of CO in hydrogen-rich gases over Ni/ZrO2 catalyst
Qihai Liu
Journal of Energy Chemistry, 2008, (03) : 268 - 272
[5] Effect of internal diffusion on preferential CO oxidation in a hydrogen-rich mixture on a copper-cerium oxide catalyst in a microchannel reactor
D. I. Potemkin
P. V. Snytnikov
V. D. Belyaev
V. A. Sobyanin
Kinetics and Catalysis, 2011, 52 : 139 - 144
[6] Effect of Internal Diffusion on Preferential CO Oxidation in a Hydrogen-Rich Mixture on a Copper-Cerium Oxide Catalyst in a Microchannel Reactor
Potemkin, D. I.
Snytnikov, P. V.
Belyaev, V. D.
Sobyanin, V. A.
KINETICS AND CATALYSIS, 2011, 52 (01) : 139 - 144
[7] Effect of ZrO2 promoter on structure and catalytic activity of the Ni/SiO2 catalyst for CO methanation in hydrogen-rich gases
Wang, Yongzhao
Wu, Ruifang
Zhao, Yongxiang
CATALYSIS TODAY, 2010, 158 (3-4) : 470 - 474
[8] The Effect of the Copper Oxide Content and Support Structure in (0.5−15%)СuО/ZrO2 Catalysts on Their Activity in the CO Oxidation Reaction with Oxygen in an Excess of Hydrogen
A. N. Il’ichev
M. Ya. Bykhovskii
Z. T. Fattakhova
D. P. Shashkin
V. A. Matyshak
V. N. Korchak
Kinetics and Catalysis, 2018, 59 : 179 - 187
[9] The Effect of the Copper Oxide Content and Support Structure in (0.5-15%)CuO/ZrO2 Catalysts on Their Activity in the CO Oxidation Reaction with Oxygen in an Excess of Hydrogen
Il'ichev, A. N.
Bykhovskii, M. Ya.
Fattakhova, Z. T.
Shashkin, D. P.
Matyshak, V. A.
Korchak, V. N.
KINETICS AND CATALYSIS, 2018, 59 (02) : 179 - 187
[10] Rhodium effect on catalytic properties of oxide systems MexOy/ZrO2 in reactions of NO reduction by hydrocarbons
Orlik, S.N.
Struzhko, V.L.
Mironyuk, T.V.
Ukrainskij Khimicheskij Zhurnal, 2002, 68 (7-8): : 32 - 36

← 1 2 →