Novel fullerene containing liquid crystalline dendrimers and hemi-dendrimers: Synthesis and characterization

被引:2
|
作者
Deschenaux, R
Yevlampieva, N
Dmitrieva, T
Dardel, B
Lavrenko, P
机构
[1] St Petersburg State Univ, Inst Phys, St Petersburg 198504, Russia
[2] Univ Neuchatel, Inst Chim, CH-2000 Neuchatel, Switzerland
[3] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
关键词
fullerene C-60; liquid crystalline dendrimers; Kerr-effect;
D O I
10.1081/FST-120027156
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Novel fullerene C-60 containing liquid crystalline dendrimers and hemidendrimers have been characterized by the method of electro-optical Kerr effect and determination of the permanent dipole moment, sensitive to the molecular polar ordering and anisotropy of polarizability, and by hydrodynamic methods in solution. An influence of the covalently bonded fullerene on the polarity. electro-optical, and viscometric properties of fullerene derivatives have been detected, analyzed, and concluded that fullerene produces a change in the original ordering in dendritic molecules, which mainly resulted in correction of the shape asymmetry of these molecules as a whole.
引用
收藏
页码:193 / 199
页数:7
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