Thermal decomposition kinetics of Ni(II) complex with norfloxacin

被引：0
|
作者：
Zhang, JJ [1 ]
Dai, YJ
Zhang, XL
Chen, HL
Ge, LG
Zhou, QZ
机构：
[1] Hebei Normal Univ, Expt Ctr, Shijiazhuang 050016, Peoples R China
[2] Shijizhuang Railway Coll, Fundamental Dept, Shijiazhuang 050043, Peoples R China
[3] Hebei Univ Sci & Technol, Fundamental Dept, Shijiazhuang 050018, Peoples R China
[4] Hebei Normal Univ, Dept Math, Shijiazhuang 050016, Peoples R China
来源：
RARE METALS | 1999年 / 18卷 / 02期
关键词：
thermal decomposition; non-isothermal kinetics; mechanisms; Ni(II) complex; norfloxacin;
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The thermal decomposition of the [Ni(NFA)(2)(NO3)2]. 2H(2)O (NFA = C16H18FN3O3, norfloxacin) and its kinetics were studied under the non-isothermal condition in nitrogen by TG-DTG: and DTA methods. The intermediate and residue for each decomposition were identified from TG curve. The Achar method and the Madhusudanan-Krishnan-Ninan (MKN) method were used to analyze the nonisothermal kinetic data. The possible reaction mechanisms were investigated by comparing the kinetic parameters. The kinetic equation for the third stage and die mathematical expressions for the kinetic compensation effects of the third stage were obtained.
引用
收藏
页码：137 / 142
页数：6
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