Kinetic Study of the Oxidation of Hydrogen Sulfide and Ethyl Mercaptan with Molecular Oxygen in the Presence of an Ammonia Solution of Cobalt Phthalocyanine Derivatives

被引：0

作者：

Kornetova, O. M. ^{[1
]}

Mazgarov, A. M. ^{[1
]}

Vildanov, A. F. ^{[1
]}

Nizamutdinova, G. B. ^{[1
]}

机构：

[1] Volga Res Inst Hydrocarbon Feedstock, Kazan 420061, Republic Of Tat, Russia

来源：

KINETICS AND CATALYSIS | 2022年 / 63卷 / 06期

关键词：

hydrogen sulfide; ethyl mercaptan; oxidation with molecular oxygen; ammonia solution of cobalt phthalocyanine derivatives; CATALYTIC-OXIDATION;

D O I：

10.1134/S0023158422060088

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The main kinetic tendencies in the individual oxidation of hydrogen sulfide and simultaneous oxidation of hydrogen sulfide and ethyl mercaptan with molecular oxygen in the presence of an ammonia solution of a substituted cobalt phthalocyanine derivative have been studied. Kinetic equations for the individual oxidation of hydrogen sulfide and simultaneous oxidation of hydrogen sulfide and ethyl mercaptan were obtained based on the experimental data, and the rate constants of the reactions were calculated.

引用

页码：773 / 780

页数：8

共 13 条

[1] Kinetic Study of the Oxidation of Hydrogen Sulfide and Ethyl Mercaptan with Molecular Oxygen in the Presence of an Ammonia Solution of Cobalt Phthalocyanine Derivatives
O. M. Kornetova
A. M. Mazgarov
A. F. Vildanov
G. B. Nizamutdinova
Kinetics and Catalysis, 2022, 63 : 773 - 780
[2] Liquid-Phase Oxidation of Hydrogen Sulfide in Oil with Molecular Oxygen in the Presence of an Ammonia Solution of Cobalt Phthalocyanine
Kornetova, O. M.
Mazgarov, A. M.
Vil'danov, A. F.
Khrushcheva, I. K.
Ayupova, N. R.
Aslyamov, I. R.
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2020, 93 (09) : 1421 - 1426
[3] Liquid-Phase Oxidation of Hydrogen Sulfide in Oil with Molecular Oxygen in the Presence of an Ammonia Solution of Cobalt Phthalocyanine
O. M. Kornetova
A. M. Mazgarov
A. F. Vil’danov
I. K. Khrushcheva
N. R. Ayupova
I. R. Aslyamov
Russian Journal of Applied Chemistry, 2020, 93 : 1421 - 1426
[4] OXIDATION OF ETHYL MERCAPTAN IN THE PRESENCE OF COBALT PHTHALOCYANINE ON A SOLID SUPPORT
PRAKHOV, LT
ANDREEV, AA
SHOPOV, DM
CHEMISTRY AND TECHNOLOGY OF FUELS AND OILS, 1986, 22 (11-12) : 606 - 609
[5] Liquid-Phase Oxidation ofn-Propyl Mercaptan with Molecular Oxygen in the Presence of an Ammoniac Solution of Cobalt Phthalocyanine
Kornetova, O. M.
Mazgarov, A. M.
Vil'danov, A. F.
Khrushcheva, I. K.
PETROLEUM CHEMISTRY, 2020, 60 (07) : 768 - 772
[6] Liquid-Phase Oxidation of n-Propyl Mercaptan with Molecular Oxygen in the Presence of an Ammoniac Solution of Cobalt Phthalocyanine
O. M. Kornetova
A. M. Mazgarov
A. F. Vil’danov
I. K. Khrushcheva
Petroleum Chemistry, 2020, 60 : 768 - 772
[7] Carboxy derivatives of cobalt phthalocyanine in liquid-phase oxidation of hydrogen sulfide by oxygen in the presence of cyanide ions
Faddeenkova, G.A.
Drugova, N.Ya.
Maizlish, V.E.
Shaposhnikov, G.P.
Kundo, N.N.
1600, Maik Nauka-Interperiodica Publishing (73):
[8] Carboxy derivatives of cobalt phthalocyanine in liquid-phase oxidation of hydrogen sulfide by oxygen in the presence of cyanide ions
Faddeenkova, GA
Drugova, NY
Maizlish, VE
Shaposhnikov, GP
Kundo, NN
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2000, 73 (05) : 820 - 823
[9] Kinetic Study of Ethyl Mercaptan Oxidation in Presence of Merox Catalyst
Ehsani, Mohammad Reza
Safadoost, Ali Reza
Avazzadeh, Reza
Barkhordari, Azita
IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2013, 32 (02): : 71 - 80
[10] Investigation of the Process of Catalytic Oxidation of Hydrogen Sulfide by Air Oxygen in the Presence of Cobalt Phthalocyanines.
Agaev, G.A.
Mukhtarov, M.M.
Aliev, N.M.
Rubinskaya, T.I.
Veliev, A.A.
Meerovich, T.P.
Amirgulyan, N.S.
Izvestia vyssih ucebnyh zavedenij. Neft i gaz, 1985, (06): : 41 - 44

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