(2,2′-Bipyridine-κ2N,N′){N-[2-oxido-5-(phenyldiazenyl)benzylidene-κO]glycinato-κ2N,O}copper(II)

被引:2
|
作者
Zhang, Qiu-Xia [1 ]
Zhao, Gan-Qing [1 ]
Zhu, Jian-Qi [1 ]
Xue, Ling-Wei [1 ]
Han, Yong-Jun [1 ]
机构
[1] Pingdingshan Univ, Sch Chem & Chem Engn, Pingdingshan 467000, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
COPPER(II); COMPLEXES;
D O I
10.1107/S1600536809036423
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cu(C15H11N3O3)(C10H8N2)], the Cu-II atom is five-coordinated in a distorted square-pyramidal CuN3O2 geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from the 2,2'-bipyridine ligand. The axial position is occupied by the other N atom of the 2,2'-bipyridine ligand. The crystal structure is consolidated by weak C-H center dot center dot center dot O hydrogen bonds. In addition, pi-pi interactions between adjacent pyridine rings (centroid-centroid distances = 3.238 and 3.313 angstrom) may also stabilize the crystal packing.
引用
收藏
页码:M1212 / +
页数:11
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