Earth-abundant metal complexes as catalysts for water oxidation; is it homogeneous or heterogeneous?

被引:56
|
作者
Asraf, Md. Ali [1 ,2 ,5 ]
Younus, Hussein A. [1 ,2 ,6 ]
Yusubov, Mekhman [3 ]
Verpoort, Francis [1 ,2 ,3 ,4 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Lab Organometall Catalysis & Ordered Mat, Wuhan 430070, Peoples R China
[2] Wuhan Univ Technol, Dept Chem Chem Engn & Life Sci, Wuhan 430070, Peoples R China
[3] Natl Res Tomsk Polytech Univ, Tomsk 634050, Russia
[4] Univ Ghent, Inchon, South Korea
[5] Rajshahi Univ, Dept Chem, Rajshahi 6205, Bangladesh
[6] Fayoum Univ, Fac Sci, Dept Chem, Al Fayyum 63514, Egypt
基金
美国国家科学基金会;
关键词
OXYGEN-EVOLVING COMPLEX; PHOTOCATALYTIC HYDROGEN EVOLUTION; INDUCED ELECTRON-TRANSFER; O BOND FORMATION; IRON COMPLEXES; PHOTOSYSTEM-II; O-2; EVOLUTION; GENERATING HYDROGEN; MOLECULAR CATALYSTS; DIMANGANESE COMPLEX;
D O I
10.1039/c5cy01251a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent developments in the oxidation of water to dioxygen using metal complexes as catalysts or precatalysts are presented, as well as the conversion of homogeneous catalysts into nanoparticles or heterogeneous catalysts during the oxidation of water. Homogeneous catalysts are advantageous in the careful design and elucidation of the mechanisms for catalytic water oxidation. In distinction, the use of heterogeneous catalysts in water oxidation is advantageous for applications as a result of their robust catalytic activity. Although detailed studies on homogeneous and heterogeneous water oxidation reactions are performed rather often, understanding the link between homogeneous catalysts and heterogeneous ones is becoming an additional requirement in order to produce economically attractive water oxidation catalysts (WOCs). This minireview focuses on the aspects that determine whether particular catalysts for the oxidation of water are homogeneous or heterogeneous.
引用
收藏
页码:4901 / 4925
页数:25
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