Stereoselective alkynylation of trans-2,3-epoxy sulfides with double inversion of configuration by alkynylaluminums

被引：18
|
作者：
Sasaki, M [1 ]
Miyazawa, M [1 ]
Tanino, K [1 ]
Miyashita, M [1 ]
机构：
[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan
来源：
TETRAHEDRON LETTERS | 1999年 / 40卷 / 52期
关键词：
epoxides; sulfides; aluminum; aluminum compounds; alkynes; stereocontrol;
D O I：
10.1016/S0040-4039(99)02013-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A stereoselective alkynylation reaction of trans-1-phenylthio-2,3-epoxyalkanes with alkynylaluminums which proceeds via episulfonium ions, that is, with double inversion of con figuration, has been developed. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：9267 / 9270
页数：4
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