Determination of Kinetic Parameters of Biomass Samples Using Thermogravimetric Analysis

被引:30
|
作者
Parthasarathy, Prakash [1 ]
Narayanan, Sheeba K. [1 ]
机构
[1] Natl Inst Technol, Dept Chem Engn, Tiruchirappalli 620015, Tamil Nadu, India
关键词
pyrolysis; thermal degradation; cellulose; hemi-cellulose; lignin; RICE HUSKS; PYROLYSIS KINETICS; ENERGY; WHEAT; WOOD;
D O I
10.1002/ep.11763
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this work, thermogravimetric analysis is carried out on four different biomass samples such as bagasse, coir-pith, groundnut shell and casuarina leaves to study their thermal behaviour. Analysis is put through in an inert nitrogen atmosphere from ambient temperature to 800 degrees C at a heating rate of 10 degrees C/min. Three reaction zones corresponding to dehydration, hemicellulose-cellulose degradation and lignin degradation are observed for all four biomass samples. The kinetic parameters such as activation energy, pre-exponential factor and order of the reaction for all the components of samples are determined using the simple Arrhenius equation. (c) 2013 American Institute of Chemical Engineers Environ Prog, 33: 256-266, 2014
引用
收藏
页码:256 / 266
页数:11
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