'Click'-BINOL based chiral ionic polymers for highly enantioselective recognition of tryptophan anions

被引：6
|
作者：
Wei, Guo [1 ]
Jiang, Yuliang [1 ]
Li, Fei [1 ]
Quan, Yiwu [1 ]
Cheng, Yixiang [1 ]
Zhu, Chengjian [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem MOE, Nanjing 210093, Jiangsu, Peoples R China
来源：
POLYMER CHEMISTRY | 2014年 / 5卷 / 18期
基金：
中国国家自然科学基金;
关键词：
ARYL-TRIAZOLE RECEPTOR; ASYMMETRIC CATALYSIS; ENANTIOMERIC EXCESS; CHEMICAL SENSORS; CHEMISTRY; POLYMERIZATION; FLUORESCENCE; BIOLOGY; ORGANOCATALYSTS; CYCLOADDITION;
D O I：
10.1039/c4py00755g
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two novel 'Click'-BINOL based chiral ionic polymers P-1 and P-2 can exhibit good enantioselective recognition behavior toward (D)-tryptophan anions with ef values up to 6.25 and 7.87, respectively. Interestingly, the fluorescence emission of P-2 shows an obvious red shift, and the solution color change could be clearly observed by the naked eye.
引用
收藏
页码：5218 / 5222
页数：5
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