A novel self-assembled supramolecular architecture involving cation, anion and a calix[4]arene heteroditopic receptor

被引：37
|
作者：
Casnati, A
Massera, C
Pelizzi, N
Stibor, I
Pinkassik, E
Ugozzoli, F
Ungaro, R
机构：
[1] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy
[2] Univ Parma, Dipartimento Chim Gen & Inorg, I-43100 Parma, Italy
[3] Prague Inst Chem Technol, Dept Organ Chem, CR-16628 Prague, Czech Republic
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 41期
关键词：
calixcrowns; ditopic receptors; anion binding; acetate receptor; potassium selective ligands; cooperativity; self-assembly; X-ray;
D O I：
10.1016/S0040-4039(02)01748-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In the presence of potassium acetate the heteroditopic calix[4]arene receptor 1, in the 1,3-alternate structure and bearing two pentafluorophenyl amide groups as anion binders and a crown-5 polyether for cation complexation, self-assembles in an unexpected 2:2:2 (calixarene:cation: anion) supramolecular structure, as shown by X-ray crystal structure. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：7311 / 7314
页数：4
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