Radical Copolymerization of N,N-Diallyl-N,N-dimethylammonium Chloride and Fumaric Acid

被引:5
|
作者
Vorob'eva, A. I. [1 ]
Spirikhin, L. V. [1 ]
Lobov, A. N. [1 ]
Galimova, S. R. [1 ]
Kraikin, V. A. [1 ]
机构
[1] Russian Acad Sci, Ufa Res Ctr, Inst Organ Chem, Ufa 450054, Bashkortostan, Russia
关键词
MALEIC-ACID;
D O I
10.1134/S1560090414030178
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The copolymerization of N,N-diallyl-N,N-dimethylammonium chloride and fumaric acid under conditions of radical initiation is studied. The reaction yields copolymers that exhibit a random distribution of comonomer units in the macrochain. Fumaric acid is highly active in the copolymerization of the above system. A significant effect on the relative activity of the comonomers is exerted by the type of solvent. The kinetics of the copolymerization is studied; the structuring of the copolymers is determined.
引用
收藏
页码:263 / 268
页数:6
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