Zeolitic Imidazolate Frameworks: Synthesis, Functionalization, and Catalytic/Adsorption Applications

被引：132

作者：

Bhattacharjee, Samiran ^{[1
]}

Jang, Min-Seok ^{[1
]}

Kwon, Hee-Jin ^{[1
]}

Ahn, Wha-Seung ^{[1
]}

机构：

[1] Inha Univ, Dept Chem & Chem Engn, Inchon 402751, South Korea

来源：

CATALYSIS SURVEYS FROM ASIA | 2014年 / 18卷 / 04期

基金：

新加坡国家研究基金会;

关键词：

Zeolitic imidazolate frameworks (ZIFs); ZIF-8; Synthesis; Functionalization; Heterogeneous catalysis; Adsorption; METAL-ORGANIC FRAMEWORKS; ROOM-TEMPERATURE SYNTHESIS; CORE-SHELL MICROSPHERES; CARBON-DIOXIDE CAPTURE; IONOTHERMAL SYNTHESIS; ZIF-8; NANOPARTICLES; WATER-ADSORPTION; DRY-GEL; CO2; MEMBRANE;

D O I：

10.1007/s10563-014-9169-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Zeolitic imidazolate frameworks (ZIFs) are comprised of transition metal ions (Zn, Co) and a range of imidazolate linkers in a tetrahedral coordination similar to that in crystalline aluminosilicate zeolites. The high surface area, tunable nanoporosity that can be subject to functionalization and the excellent thermal/chemical stability of ZIFs are attractive for heterogeneous catalysis and selective gas adsorption/separation. This review presents the current trends in synthesis, surface modification and catalytic reactions/adsorption of ZIF-based materials with particular emphasis on ZIF-8, which is the most widely studied structure among ZIFs.

引用

页码：101 / 127

页数：27

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