Optical anion sensors based on alkyne-linked, functionalized calix[4]pyrroles

被引：17
|
作者：
Miyaji, H
Sato, W
An, DQ
Sessler, JL
机构：
[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA
[2] Univ Texas, Inst Mol & Cellular Biol, Austin, TX 78712 USA
来源：
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2004年 / 69卷 / 05期
关键词：
anion complexation; anion receptors; sensors; calixpyrroles; alkynes; pyrroles; supramolecular chemistry; fluorescence;
D O I：
10.1135/cccc20041027
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Linking a calix[4] pyrrole anion recognition subunit to chromophores or fluorophores via an alkynyl spacer attached to a beta-pyrrolic position of a calix[4] pyrrole core produces a new class of anion sensor that permits the detection of halide and phosphate anions in organic media via direct, so-called "naked-eye" visualization or fluorescence quenching-based spectroscopic means.
引用
收藏
页码：1027 / 1049
页数：23
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